Redox and redox equilibria
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- I am currently investigating the iodine clock reaction involving hydrogen peroxide. I don't understand how to work out if the overall equation is redox, especially in view to oxidation numbers? I also understand that the overall reaction can be split into 'half-equations' but am not sure how to go about this. 210208
- I'm doing my background chemistry for a redox titration to determine the concentration of copper ions using potassium iodide. I know the ionic equation I need is: 2Cu2+(aq) + 4I-(aq) -> 2CuI(s) + I2(aq) I'm having problems explaining why this reaction occurs though because my two half-equations are: Cu2+(aq) + e- ->Cu+(aq) - Eo = 0.15 V I2(aq) + 2e- -> 2I-(aq) - Eo = 0.54 V The Eo values would normally mean I would reverse the Cu half-cell as it has the more negative Eo value. But to get my overall ionic equation I actually need to reverse the iodine half-cell. So I'm confused why the reaction occurs. Vikki
- Hi, I hope you can help me. thank you. 1.What are the significant regions in a titration curve and what are the characteristics of these regions? 2.What are the differences in the Veq values obtained? 3.How is the end-point estimated using potentiometric titration if no chemical indicator is added? 4.What is the importance of continuous stirring in potentiometric titration? 5.Why should the increments of addition of titrant be narrowed down as the titration proceeds and approaches the equivalence point? 6.What are the advantages of using potentiometric titration? 7.What are the possible sources of error? 130808
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updated: 21 August 2003

