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I'm doing my coursework on the thiosulpate-acid expt. What is the shape of the thiosulphate ion, and does how the mechanism for the reaction work?

Ulex writes ...
 
The thiosulphate ion is very similar in shape to the sulphate ion, with one oxygen atom replaced by a sulphur atom. The sulphate ion is exactly tetrahedral, so the thiosulphate ion is a slightly distorted tetrahedron.
 
I believe that the reaction is first order with respect to each of thiosulphate and hydrogen ion, but beyond this I do not know what has been done to elucidate the mechanism.

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updated: 25 February 2004

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