Nuffield Advanced Chemistry Re:act

You are in: Home > Recently Asked Question

 Practical investigations

Read our general notes on Risk Assessment

I am doing the iodine clock test as an investigation. My reactants are sodium thiosulphate, starch, HCl, potassium iodide and hydrogen peroxide. At the end when a starch iodine complex forms is it a coloured organic compound with delocalised electrons, if so is it correct to call it a complex?
Also where can I research what the order of my reaction is with respect to the hydrogen ions?

Jenkin says
 
It certainly doesn't consist of a central metal ion bonded to a number of ligand molecules or ions by lone pairs of electrons, so it isn't a complex in that sense. I think the word complex here means just a complicated species.
 
It is sometimes described as an adsorption complex, suggesting that iodine molecules are concentrated on the surface of starch molecules, but iodide ions are almost certainly involved, as well as the colour is visible at extremely low iodine concentrations. One of my references (Pine, Hendrickson, Cram and Hammond, Organic Chemistry) suggests it is a 'complex' (their word) formed when an I5- species is held within the very long, spiral, starch molecule.
 
Igloo adds
 
I agree with Jenkin about the starch iodine complex. The intense blue-black colour formed when starch and iodine interact is not strictly a “complex” with a fixed structure, but is a relatively “loose” clathrate or cage arrangement involving iodine in the form of I5- ions being trapped in the coils of the beta amylose molecules of starch.
 
You will find more details at this web site.
 

As for the kinetics of the reaction between iodide ions, hydrogen peroxide molecules and hydrogen ions, the process, according to : this web reference is first order with respect to hydrogen ions.
 

Risk assessment
Before attempting any practical work based on the advice and suggestions on this website, you must do the following. Identify any hazards, assess the risks from these hazards, and then decide appropriate control measures to reduce the risks. You must have these approved by those in authority in your school or college laboratory. Do not rely on what is said on this website. For further guidance see our tutorial on Risk Assessment.

back to Practical investigations


Rate this page or react
Share your views on this page, 1 ratings so far , rated at 1 Stars

1 Star
1 Star
3 Star
4 Star
5 Star


updated: 10 March 2006

Chemistry Search



Questions and Answers
You can search the Re:act site here. If this search does not give you the information you need, then you can ask a question and we will try to help you.

You Tell Us

You Tell Us - ideas, information and suggestions