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If possible can you just give me examples of substances that would have: van der Waals' forces, hydrogen bonding, permanent dipoles and dipole-dipole attractions.
130408

Corrie writes ....
 
van der Waals' forces only: between non-polar molecules, such as hydrocarbons, halogens, Noble Gases, CO2 etc
 
Hydrogen bonding: between molecules that contain a H-atom attached to a F, O or N atom, such as H2O, HF, NH3, H2O2, CH3OH etc
 
Dipole-dipole forces: between molecules that are polar, i.e have a permanent overall dipole, such as H-Cl, H2C=O, OF2 etc.
 
REMEMBER that:
 
1. All molecules, whether non-polar or polar, experience attraction due to van der Waals' forces but for small molecules this contribution to the attraction is usually less than that from dipole-dipole attraction, and much less than that from H-bonding, if also present.
 
2. Small molecules capable of hydrogen bonding are usually also polar, e.g. H2O and will experience dipole-dipole attraction and van der Waals' forces as well, but the H-bonding attraction is by far the strongest attraction.
 

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updated: 13 April 2008

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