Redox and redox equilibria
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- I am currently investigating the iodine clock reaction involving hydrogen peroxide. I don't understand how to work out if the overall equation is redox, especially in view to oxidation numbers? I also understand that the overall reaction can be split into 'half-equations' but am not sure how to go about this. 210208
- I'm doing my background chemistry for a redox titration to determine the concentration of copper ions using potassium iodide. I know the ionic equation I need is: 2Cu2+(aq) + 4I-(aq) -> 2CuI(s) + I2(aq) I'm having problems explaining why this reaction occurs though because my two half-equations are: Cu2+(aq) + e- ->Cu+(aq) - Eo = 0.15 V I2(aq) + 2e- -> 2I-(aq) - Eo = 0.54 V The Eo values would normally mean I would reverse the Cu half-cell as it has the more negative Eo value. But to get my overall ionic equation I actually need to reverse the iodine half-cell. So I'm confused why the reaction occurs. Vikki
- I am investigating the rate of reaction between manganate(VII) and oxalate ions. I am using the colorimeter. It takes time to put the solution into a cuvette. How could i make this accurate? Could I start recording the absorbance after 20 s for each solution to make it fair? I was also wondering how I would investigate the autocatalytic effect. I know I would use MnO, but what do I do with it - vary the concentration maybe? 091008
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updated: 21 August 2003

