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I am currently doing an investigation on the purity of aspirin. I have found that the melting point of aspirin is about 135 °C. However, when I crushed a SOLUBLE aspirin tablet to test the melting point the sample did not melt even at 200 °C. Can you tell me whether soluble aspirin has a different melting point and why it does not melt at 135 °C?

Igloo replies
 
Aspirin is a covalent compound and an acid, whereas “soluble aspirin” is the sodium salt of aspirin, and is therefore ionic. The relatively strong ionic forces in a soluble aspirin tablet cause its melting point to be much higher than that for aspirin itself.

Risk assessment
Before attempting any practical work based on the advice and suggestions on this website, you must do the following. Identify any hazards, assess the risks from these hazards, and then decide appropriate control measures to reduce the risks. You must have these approved by those in authority in your school or college laboratory. Do not rely on what is said on this website. For further guidance see our tutorial on Risk Assessment.

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updated: 18 January 2006

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