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How do you work out the standard enthalpy change of formation?

Ulex replies ... Begin by writing the equation for the formation of the substance concerned from its elements
 
C(s) + 2H2(g) -> CH4(g)
 
You want the enthalpy change for this reaction.
 
Next, think out what you can do to the substances on both sides of the equation which will result in the same products. In this case, the simplest thing is to burn them. It is possible to do all the combustion reactions in a calorimeter and to measure the enthalpy changes.
 
Set up a Hess triangle with the equation above and with the combustion products at the third point of the triangle. Solve this triangle to get the required enthalpy change.

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updated: 02 March 2004

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